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MICELLAR CATALYZED REACTION IN AQUEOUS GLYCEROL SOLUTIONS AND THE INTERNAL PRESSURE OF THE MEDIUM
Volume: 16
Number: 16
Year: 2008
Pages: 41-57
Lavinel G. Ionescu, Vera Lucia Trindade and Elizabeth Fatima de Souza
Abstract:
<p align="justify"> The experimental results obtained/or the hydrolysis of p-nitrophenyl diphenyl phosphate (NPDPP) in the presence of sodium hydroxide (NaOH), micelles of cetyltrimethylammonium bromide (CTAB), and an aqueous solution of glycerol were analyzed taking into consideration the internal pressure and the cohesive forces of the reaction medium. The effect of glycerol on mice/le formation and also its influence on the internal pressure of the reaction medium are large enough to affect the micellar catalyzed alkaline hydrolysis of the phosphate ester. </p>
DOI: 10.48141/SBJCHEM.v17.n17.2008.43_2008.pdf
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