KINETICS OF OXIDATION WITH HYDROGEN PEROXIDE AND IRON(II) COMPLEX WITH A MACROCYCLIC BINUCLEATING LIGAND
Abstract:
<p align="justify"> In the present study solutions of a complex of Fe(II) with a macrocyclic ligand were prepared and their oxidation kinetics with hydrogen peroxide examined. The kinetic studies of the oxidation processes lead to values of rate constant of two-step which occur via first-order kinetics. The results are expected to result in a better knowledge of the mechanism of H<sub>2</sub>0<sub>2</sub> activation in catalyzed oxidation of organic substrates. </p>
<p align="justify"> In the present study solutions of a complex of Fe(II) with a macrocyclic ligand were prepared and their oxidation kinetics with hydrogen peroxide examined. The kinetic studies of the oxidation processes lead to values of rate constant of two-step which occur via first-order kinetics. The results are expected to result in a better knowledge of the mechanism of H<sub>2</sub>0<sub>2</sub> activation in catalyzed oxidation of organic substrates. </p>
DOI: 10.48141/SBJCHEM.v3.n3.1995.57_1995.pdf
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