MOLECULAR MODELING, REACTIVITY PARAMETERS, AND SPECTROCHEMIC STUDIES OF e-CAPROLACTAM AND o-PHENANTROLINE
Background: Recently, research has been carried out to improve the efficiency of electronic devices in general. With the commercial search for consolidated materials and the growth in demand with monitoring of costs, research has sought to minimize these effects with the replacement or functionalization of other substances, which may be applied at lower costs without compromising operating yields already achieved. Objective: This work aimed to obtain molecular modeling and reactivity parameters of -caprolactam and o-phenanthroline to evaluate the interaction capacity in the formation of molecular systems. Conductance measurements were taken to observe the electrolytic behavior. Infrared and UV-visible spectra were recorded to characterize vibrational transitions and evaluate spectrochemical properties. Methods: The WebLab program was used to obtain structural data and calculate reactivity parameters. Conductance was obtained in QUIMIS Q-405 equipment. IR spectra were recorded on PERKIN ELMER FRONTIER equipment. UV-vis spectra were recorded in a SHIMADZU equipment 200 – 1000 nm range to record the main transitions. Results and Discussions: Electron donor atoms are centered mainly on oxygen and nitrogen, respectively, which are sterically more favorable. The behavior was non-electrolyte. Groups with vibrational transitions sensitive to chemical interactions are comprised of C=N, C-N, and C=O bonds. The parameter indicates transitions in the 190 – 300 nm region and the near-infrared, and the oscillator strength is typical of molecules used as dyes and sensitizers in optical light-emitting systems or light-to-electricity converters. Conclusions: We observed that these ligands have a donor capacity for the formation of complex systems that meet the need for electron transfer in optical pumping devices for the intensification of transitions or radiation converters, which can also be applied in radiation-to-electricity converter systems.
Read ArticlePRODUCTION OF BIOPLASTIC FROM POTATO STARCH
Due to their diverse properties, plastic materials are used in numerous sectors. It is possible to produce different articles and plastic objects with reduced costs, being more accessible to the population. Conventional plastics are obtained from petroleum-derived raw materials, a non-renewable resource in which their extraction and refining process cause major environmental impacts. The production of plastic reaches a level of approximately one hundred and forty million tons per year, and the disposal of these materials is increasing, generating a high rate of waste and leading to an increase of pollution since the decomposition of these materials lasts about five hundred years old. Conventional plastics can be replaced by bioplastics, a material obtained from renewable raw materials such as potatoes, cassava, maize, and which, when disposed of under favorable conditions, decomposes faster, as during its degradation process at least one step occurs. Through the metabolism of organisms present in the environment. Starch has been widely used in the production of biodegradable packaging, so the objective of this work was to produce a biodegradable bioplastic from the potato starch. Potato starch, glycerin, hydrogen peroxide, distilled water, and commercial agar were used to produce the bioplastic. Bench-scale bioplastics had good organoleptic characteristics, similar in appearance to a conventional plastic obtained from petroleum. The thickness, moisture content, and solubility of the bioplastics were analyzed, as well as their fruit preservation capacity. The samples produced were rigid and with good resistance.
Read ArticleSECOND SOUTHERN SCIENCE CONFERENCE - INTERNATIONAL SCIENTIFIC CONFERENCE – 2024
Background: Scientific conferences play a vital role in knowledge exchange and collaboration across disciplines. Building on the success of its 2022 inaugural event, the Second Southern Science Conference (SSCON 2024) aimed to expand international scientific collaboration while addressing contemporary challenges in sustainability and research methodology. Aims: To evaluate the effectiveness of a hybrid conference format in facilitating global scientific collaboration and to showcase cutting-edge research across multiple disciplines, with particular emphasis on sustainability and technological innovation in Latin America. Methods: The conference implemented a hybrid format combining in-person and virtual attendance. Over three days, 38 lectures were presented by renowned researchers, covering key topics including materials science, environmental sustainability, chemical processes, and regional development. Participation metrics and collaboration patterns were analyzed to assess the conference's impact. Results: The conference achieved significant participation with 242 contributing authors from 13 countries across four continents. Notable research presentations included advances in laser surface modification techniques, geotechnology applications in biofuel production, sustainable silica synthesis from biomass, and green valorization of tropical seeds. The conference produced 66 approved papers, with most involving 2-5 collaborators. Discussion: The hybrid format proved effective in removing geographical barriers and promoting global engagement. The strong representation from Latin American institutions highlighted the region's growing influence in international scientific discourse. Key research presentations demonstrated innovative approaches to sustainability challenges, particularly in waste utilization and environmental technology. Conclusion: SSCON 2024 successfully evolved from its predecessor, demonstrating the effectiveness of hybrid conferencing in fostering international scientific collaboration. The conference established itself as a vital platform for knowledge exchange, particularly in sustainability and technological innovation, while identifying areas for future improvement such as extended submission timelines and permanent management structures.
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