EXTRACTION AND CHARACTERIZATION OF CURCUMIN FROM TURMERIC RHIZOMES GROWN IN MÉRIDA, VENEZUELA
The extraction of naturally occurring compounds is one of the fastest-growing industries because of its benefits against its synthetic analogs. Environmental protection must require the use of natural products instead of chemicals to minimize pollution. Thus, this investigation studies the use of some natural product, as curcumin, as naturally occurring acid‐base indicators. Curcumin can be used as acid-base indicators since it was found that it possesses pH-dependent solubility. Curcumin, the major active component of turmeric, Curcuma longa (Zingiberaceae), is used as a spice in curry and as a coloring agent in yellow mustards, cosmetics, pharmaceuticals, and hair dyes. In this research, the main compound colored rhizome of turmeric (Curcuma longa) cultivated in Mérida, Venezuela, is extracted: Curcumin (C21H20O6) (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione, in a yield of 3.42% after 8 hours of extraction using soxhlet extractor system with organic solvents (hexane and ethanol). The thin-layer chromatography and column performed separation and purification using a mobile phase, a mixture of chloroform-hexane 3:2. The dye was characterized by spectroscopic analysis of visible ultraviolet (UV-Vis) and infrared (IR), in addition to his studio in steering sensitivity as an acid-base indicator. This dye is useful as an acid-base indicator in strong acid-strong base volumes and did not require large amounts of it as it has high sensitivity. The results indicate that curcumin as an acid-base indicator allows the development of new standards in different chemistry fields that require this type of analysis.
Read ArticleHEAT DISSIPATION AT CEMENT HARDENING
During the construction of concrete structures of small cross-sections, the release of heat during cementhardening has no harmful effects. With the increasing temperature of the hardening cement mass, the rate ofcement hydration increases. This increases the rate of release of its heat of hydration of cement. Theconsequence of the accelerated process of hydration of the binder is a more intensive increase in the strengthof cement stone than in the case of hardening under normal conditions. This fact is widely used in practice forthe intensification of the hardening of concrete. When structures with small cross-sections are being built, theheat released during hardening is relatively quickly transferred to the surrounding space and does not cause asignificant increase in temperature. In structures made of massive concrete (with a large cross-section), thisheat is stored in the interior of the array for a long time, which causes a rather large rise in temperature and itsslow drop. This is due to the fact that heat transfer to the external environment is hampered here by theconsiderable thickness of the massif and the rapid rate of concreting, mechanized laying of large masses ofconcrete. As a result, a temperature difference is created between the internal and external parts of thestructure and harmful internal stresses arise that can cause cracking in the hardened concrete. This leads to aviolation of its solidity. The faster cement hydrates, the sooner and more heat is released. The types of cementswith a high content of tricalcium silicate and aluminate emit more heat and rather than types of cement with ahigh content of dicalcium silicate and tetra-calcium aluminoferrite. However, the latter has a lower strength. Theincrease in strength resulting from the hydration process is inevitably associated with the release of heat into theenvironment. C
Read ArticlePRODUCTION OF BIOPLASTIC FROM POTATO STARCH
Due to their diverse properties, plastic materials are used in numerous sectors. It is possible to produce different articles and plastic objects with reduced costs, being more accessible to the population. Conventional plastics are obtained from petroleum-derived raw materials, a non-renewable resource in which their extraction and refining process cause major environmental impacts. The production of plastic reaches a level of approximately one hundred and forty million tons per year, and the disposal of these materials is increasing, generating a high rate of waste and leading to an increase of pollution since the decomposition of these materials lasts about five hundred years old. Conventional plastics can be replaced by bioplastics, a material obtained from renewable raw materials such as potatoes, cassava, maize, and which, when disposed of under favorable conditions, decomposes faster, as during its degradation process at least one step occurs. Through the metabolism of organisms present in the environment. Starch has been widely used in the production of biodegradable packaging, so the objective of this work was to produce a biodegradable bioplastic from the potato starch. Potato starch, glycerin, hydrogen peroxide, distilled water, and commercial agar were used to produce the bioplastic. Bench-scale bioplastics had good organoleptic characteristics, similar in appearance to a conventional plastic obtained from petroleum. The thickness, moisture content, and solubility of the bioplastics were analyzed, as well as their fruit preservation capacity. The samples produced were rigid and with good resistance.
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