COMPARISON OF TWO STAINING METHODS FOR ANODIZING IN ALLOY 6063 ALUMINUM PROFILES
Background: Aluminum stands out for being a light, corrosion-resistant, and recyclable metal, achieving wide coverage in the market. When incorporated into alloying elements, it is possible to acquire other desirable characteristics. Alloy 6063, intended for architectural purposes, has aesthetic, structural, and strength functions. Anodized finishing is performed through an electrolytic process, ensuring a more resistant aluminum oxide film than that formed naturally. For decorative purposes, the anodic film coloration can be performed by several methodologies, in this case, for the coloration by organic adsorption, with the use of aniline, and the electrolytic coloration, composed of tin sulfate salts, both for obtaining the black color. Aim: Compare of two different staining methods on the surface of anodized profiles of aluminum alloy 6063. Methods: Profile samples were collected and tests were carried out to measure the thickness of the anodic layer, immersion tests with 3,5 percent sodium chloride, for 1000 hours, and neutral saline mist, for 600 hours. Results and Discussion: Both methodologies proved to be resistant to immersion tests with sodium chloride, as well as with neutral saline mist, and these tests are quite aggressive and provide corrosion of the material when not well treated. Corrosion points were only seen at the intersections performed, and in the rest of thearea, no points were detected. Conclusions: The result of both methodologies was positive, considering tht there was no corrosion in the tested samples, except in the intersections performed, as well as the maintenance of the color in both tested methodologies, which was not expected in the literature. For future work, it is suggested to deepen the study to perform electrochemical impedance spectroscopy tests for exaluate the strength of the anodic film and perform anodizing with the same parameters, however, with different anilines to analyze their behavior.
Read ArticleENTREPRENEURSHIP, INNOVATION, AND COMPETENCY-BASED EDUCATION - INTERVIEW WITH PROF. PAULO CÂMARA. ENGLISH VERSION
Background: The interview was conducted with Professor Paulo Wilton da Luz Câmara, who serves as an associate professor at the University of Vassouras, general coordinator of postgraduate lato sensu programs, and deputy coordinator of the Master's in Environmental Sciences. The Professor has extensive academic and corporate experience. Objectives: The main objectives were to understand the importance of corporate experience in the role of a professor and researcher, discuss the evolution of public entrepreneurship policies in Brazil, understand the role of incubators, explore research on renewable energies in the defense sector, and learn about planned innovations for postgraduate programs. Methods: The interview was conducted in a semi-structured format with open-ended questions. The audio was transcribed for subsequent analysis and content structuring. Results: Corporate experience significantly influences academic performance. There has been relative improvement in public entrepreneurship policies, but the involved bodies lack specific knowledge. Incubators are necessary tools to foster entrepreneurship and innovation. The main challenges in renewable energy research for defense are awareness and organizational policy. Planned innovations for postgraduate programs include connecting education levels, shared management, and an open committee. Discussion: The Professor highlights the importance of practical corporate experience in enriching academic performance, noting advances in entrepreneurship policies while emphasizing the need for more specific knowledge. Incubators are seen as essential to fostering entrepreneurship and innovation. In the field of renewable energy applied to defense, challenges are related to awareness and organizational policy. Conclusion: The interview underscores the relevance of practical corporate experience in enriching academic performance and the need to improve entrepreneurship policies. Incubators are fundamental to fostering entrepreneurship and innovation. Research on renewable energies in defense faces challenges of awareness and organizational policy. Planned innovations for postgraduate programs aim for greater integration and participation.
Read ArticleEFFECT OF MECHANICAL ACTIVATION ON THE POTASSIUM AVAILABILITY OF PHONOLITE ROCK
Background: Researchers are carried out to assess rocks containing potassium as an alternative source of fertilizers. These studies are important in reducing the external dependence of Brazil on this commodity. Phonolite is a rock of volcanic origin that has in its mineralogical composition the predominance of feldspar and has been potential to use as an alternative potassium source. The studied rock has 6% total-K but is unavailable to plants in natural rock. Aim: This project evaluated the effect of mechanical activation, wet and dry, on K availability for extractors different and its K leaching curves of phonolite from Poços de Caldas, MG, Brazil. Methods: Phonolite rock was subjected to mechanical activation for 30 and 60 min by wet and dry processes. Particle size distribution, XRD, and FTIR analyses characterized phonolite activated. These results were compared to the behavior of the rock with no activation. K availability (total; water-soluble; exchangeable, non-exchangeable, and structural) was determined in samples activated and no activation. K leaching curves were obtained by successive extractions with 0.01 mol L-1 citric acid and Mehlich-1 solutions to 1812 h and analyzed by FAAS. Results: The samples mechanical activation promoted a reduction in the intensity of the diffraction peaks. In the sample dry mechanical activation for 60 min, K released increased by 15% in relation to the no activation sample. K leaching curves were observed with similar behavior for the extractors and higher K availability after 235 h of total contact time. Discussion: Mechanical activation promoted a decrease in structural K and an increase in non-exchangeable K, released into the soil solution in the medium term. Since the mineralogical composition was not changed, the process action is more efficient in creating the structural defects suggested. K leaching curves corroborate these results, with a continuous and slow K released for a longer contact time. Conclusions: It was concluded that the phonolite activated by dry mechanical activation for 60 min increased K-released content compared with the wet process and ratified the possibility of the activated phonolite rock as a slow-release fertilizer.
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